Number every order
Use a simple sequence (PO-0001, PO-0002...) and ask suppliers to quote it on their delivery notes and invoices. No PO number, no payment.
Record what was agreed
Supplier, items, quantities, price, delivery date and who approved it. Agree a spending limit above which someone else signs off.
Chase deliveries
Keep an eye on orders past their delivery date and chase them before they hold up the job.
Match before you pay
Check the invoice against the PO and the delivery: right items, right quantities, right price. Only then mark it to pay. That one step catches most overcharges and duplicate invoices.
Close it off
Mark the order paid with the date and invoice reference, so the log shows what's still outstanding at a glance.